If both ends of the piping are fixed, you may have to cut it out, add a new piece of copper tubing to make up list length, and sweat-solder your new valve into place. This looks to me like a case of someone using adapters so they could solder in the valve they had in hand /, rather than using a threaded valve because they actually wanted to be able to disassemble it
You could probably get away with cutting one side free, unscrewing the other, and using another threaded valve with a soldering adapter attached on the end you're going to resolder, nut I'm not convinced that is any improvement over just getting a soldered-in valve body.
Quick tip: Sweating pipe is MUCH less stressful with an instant-on/instant-off torch. If you haven't sweated pipe before, getting a foot or two of pipe and a few cheap connectors will let you practice before doing it for real. Critical steps are cleaning the surface adequately and getting the joint hot enough before applying solder. There are lots of good videos on the net to learn from.