Disclaimer, I don't own such a bulb. This is straight color theory and design.
LED bulbs such as your smart bulb use additive color. They operate by combining Red/Green/Blue light at varying intensities to create the 16 million combinations given in the specs.
Your wall paint works with subtractive color or pigments. They work by absorbing some R/G/B light and reflecting the rest. So your blue wall actually absorbs mostly red and green, reflecting blue back to your eye.
This means that when your LED is adding colors that more heavily rely on red and green (yellows and oranges), they won't look as appealing on your blue wall. This is because little if any blue is emitted, so little if any blue is reflected. On top of this, the wall still reflects some red and green as usual, and mixing it altogether leads to unattractive browns and greys. You can test this by changing your bulb to pure green and shining it on a red object, such as an apple, with no other light. The apple will likely look unattractive and greyish.
Change your wall to any other color, and the same thing will happen, except you've just adjusted which portion of the color wheel is affected. Darker walls will be more adversely affected because dark walls, by nature, already reflect less or absorb more of the light coming at them.
So, if your goal is to have your walls look pleasant under any of the 16 million color possibilities, assuming they're all pleasant, then lighter neutral shades or white are your best bet. This is because they will reflect back the most even light. The goal is to not have the pigment of the wall muddy the color by unevenly absorbing and reflecting the light shone on it.
However, 16 million colors is quite a color palette to try and coordinate a room around, and walls are not the only points of color. Furniture, decor and other accents may also play a factor in your decision. If you'd like to use a certain color palette in your decorating, then you may want to consider limiting your use of the LED's spectrum.
If that's the case, you could venture into some wall colors that take advantage of the spectrum you do use. For instance, if you decide to eliminate yellow from the LIFX, then there's a wider variety of blue wall hues that'd look pleasant under the remaining lights.