I know that veloute/espagnole is fundamentally roux and stock. Stock is basically salt, flavoring, and water. I was building a Japanese-inspired recipe, and I was curious how replacing stock with soy sauce would affect the resulting mixture.
I made a roughly 1:1 white roux with AP flour and neutral oil (a random mixture of LT olive and canola), heated approximately 1 part soy sauce in the microwave, added a spoonful of roux to the soy sauce to temper it (probably unnecessary since the soy was already hot) then combined all ingredients and stirred.
The mixture immediately thickened up into a paste. It was not clumpy and still had a good texture on my palate. I was easily able to get the mixture to relax back into a gravy by adding vegetable stock.
I recall seeing the mixture strongly foam up when I added the soy sauce, which is interesting. Kikkoman mentions that their soy sauce contains around 2% ABV, and I know that evaporative action can cause foaming. I doubt whatever chemical change happened was primarily heat-mediated--the thickening happened rather quickly. I had done this once before, but using cold soy sauce, and the foaming happened but the roux broke from the cold.
So what happened? I'm looking for answers that explain the underlying mechanism, so I can generalize and apply the knowledge in the future.