Look at The Periodic Table. Metal (Group I and II) hydroxides are bases, non-metal "hydroxides" are acids (especially with high positive charges on the non-metal.) Then we have amphoteric hydroxides like zinc and aluminum that afford zincates and aluminates in very alkaline media. $\ce{Mn(OH)3}$ is a base but $\ce{HOMnO3}$ is a strong acid. Look at core oxidation state, charge polarization, and oxophilicity of that ion.
Arrhenius, Brønsted-Lowry, Lewis; hard, soft; solvo-cation, solvo-anion. How do you classify $\ce{Al(OMe3)}$ that is a Brønsted base for methoxide and a Lewis acid for aluminum(III)?
$\ce{NH4}{^+}$ $\ce{NH3}$ $\ce{NH2}{^-}$ $\ce{NH}{^{2-}}$ $\ce{N}{^{3-}}$. Ammonium is definitely the acid. Nitride is definitely the base. What are the species in-between?