I've put those two parts side by side in LeoCAD, and it's quite obvious they have different shapes:

A side view illustrates the difference even more clearly:

They will somewhat align if one of the ramps is rotated exactly eleven degrees, like in the following diagram:

Do note that while it's easy to align bricks at increments of 15 degrees with hinge parts (and a few other amounts by resting over sloped bricks), eleven degrees is a hard angle to achieve.
As user @SanderDeDycker pointed out, it's also possible to align the ramps without rotating them, with a vertical offset of slightly less than 2 plates, and a horizontal offset of about 2.3 studs - again, dimensions that are hard to achieve:

Applying a bit more CAD, I estimate the radius of the slope to be 11½ studs. Note how, in the following diagram, the left tangent line crosses the last stud of the grey ramp; and that the grey ramp is 12 studs deep.

A bit more fiddling with CAD tells me that the "new" ramps (75538) have a slope radius of 12 studs instead.
Please keep in mind that my measurements are based on the LDraw models, and I have spent very little time on them, so they might not accurately reflect the dimensions of physical bricks.