Google Scholar is actually quite useful, insofar as it draws a broad net for publications, whereas many other citation databases fail to capture important papers. Unfortunately, Google Scholar also has some problems with double-counting, since it often treats different versions of the same articles as if they were different publications, which can artificially inflate citation count. A secondary problem with Google Scholar (which also applies to other citation databases) is that it gives "raw" citation counts (and derived metrics like H-index, etc.) rather than "author adjusted" metrics. This also artificially inflates citation count, especially for authors who do most of their work with a substantial number of co-authors.
One problem with Google Scholar is that its broad sources for papers means that it can be subject to manipulation by publishing mock papers that give no scholarly contribution but give citations to other works or to each other (see e.g., López-Cózar et al 2012). The more tightly curated citation databases do not have this problem since they only count publications in approved sources; typically these sources are established scholarly journals with effective peer review processes.
As the other answer here points out, none of the citation databases are very good. They all suffer from under- or over-coverage and most do not make a serious attempt to adjust metrics for authorship. Personally, I think Google Scholar is less bad than many of the others, since it at least captures all the important papers a person has written, rather than artificially excluding those that fall outside a narrow range of journals. However, you should be aware of its drawbacks in relation to other citation databases and ensure that you carefully inspect the individual publications when using it as an evaluative source.